Synthesis, Characterization and Spectroscopic Study of New Metal Complexes form Heterocyclic Compounds for Photostability Study
Abstract
Ali M. A. Al-Khazraji, Rehab A. M. Al Hassani.
In present project, new Schiff base of 4, 4'- (((1E, 1'E)-1,4-.phenylenebis- (methane-ylylidene))-bis-(azane-ylylidene)) bis-(5-(4-chlorophenyl) -4H -1,2,4-triazole-3-thione) (L3) has been synthesized by condensation of 4-amino-5-(4-chlorophenyl)-2,4-dihydro-3H-1,2,4-triazole-3-thione with benzene-1,4-dicarboxaldehyde. The new asymmetrical Schiff base (L3) used as a ligand to synthesize a new complex with Co(II), Ni(II), Cu(II), Pd(II), and Pt(IV) metal ions by 1:2 (Metal: ligand) ratio. New ligand and their complexes have been exanimated and Confirmed by Fourier-transform infrared (FT-IR), Ultraviolet-visible (UV-visible), Proton nuclear magnetic resonance (1HNMR), carbon13 nuclear magnetic resonance (13CNMR), carbon-hydrogen nitrogen sulfur (C-H-N-S), thermal analysis (TG), atomic-absorption-flame (AAF), cond-uctivity and Magnetic susceptibility. Examining new compounds through a calculation of photodegradation polystyrene films, assessed photo-stability activities. Results indicate Pt2L3 > Pd2L3 > Cu2L3 > Ni2L3 > Co2L3 > L3 > PS. Polymer stability is given for this the analysis of the reduction of weight, molecular average, reveals a more stable polystyrene PS.
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| Pubmed Style Ali M. A. Al-Khazraji, Rehab A. M. Al Hassani. Synthesis, Characterization and Spectroscopic Study of New Metal Complexes form Heterocyclic Compounds for Photostability Study. SRP. 2020; 11(5): 535-555. doi:10.31838/srp.2020.5.71 Web Style Ali M. A. Al-Khazraji, Rehab A. M. Al Hassani. Synthesis, Characterization and Spectroscopic Study of New Metal Complexes form Heterocyclic Compounds for Photostability Study. http://www.sysrevpharm.org/?mno=119517 [Access: March 29, 2021]. doi:10.31838/srp.2020.5.71 AMA (American Medical Association) Style Ali M. A. Al-Khazraji, Rehab A. M. Al Hassani. Synthesis, Characterization and Spectroscopic Study of New Metal Complexes form Heterocyclic Compounds for Photostability Study. SRP. 2020; 11(5): 535-555. doi:10.31838/srp.2020.5.71 Vancouver/ICMJE Style Ali M. A. Al-Khazraji, Rehab A. M. Al Hassani. Synthesis, Characterization and Spectroscopic Study of New Metal Complexes form Heterocyclic Compounds for Photostability Study. SRP. (2020), [cited March 29, 2021]; 11(5): 535-555. doi:10.31838/srp.2020.5.71 Harvard Style Ali M. A. Al-Khazraji, Rehab A. M. Al Hassani (2020) Synthesis, Characterization and Spectroscopic Study of New Metal Complexes form Heterocyclic Compounds for Photostability Study. SRP, 11 (5), 535-555. doi:10.31838/srp.2020.5.71 Turabian Style Ali M. A. Al-Khazraji, Rehab A. M. Al Hassani. 2020. Synthesis, Characterization and Spectroscopic Study of New Metal Complexes form Heterocyclic Compounds for Photostability Study. Systematic Reviews in Pharmacy, 11 (5), 535-555. doi:10.31838/srp.2020.5.71 Chicago Style Ali M. A. Al-Khazraji, Rehab A. M. Al Hassani. "Synthesis, Characterization and Spectroscopic Study of New Metal Complexes form Heterocyclic Compounds for Photostability Study." Systematic Reviews in Pharmacy 11 (2020), 535-555. doi:10.31838/srp.2020.5.71 MLA (The Modern Language Association) Style Ali M. A. Al-Khazraji, Rehab A. M. Al Hassani. "Synthesis, Characterization and Spectroscopic Study of New Metal Complexes form Heterocyclic Compounds for Photostability Study." Systematic Reviews in Pharmacy 11.5 (2020), 535-555. Print. doi:10.31838/srp.2020.5.71 APA (American Psychological Association) Style Ali M. A. Al-Khazraji, Rehab A. M. Al Hassani (2020) Synthesis, Characterization and Spectroscopic Study of New Metal Complexes form Heterocyclic Compounds for Photostability Study. Systematic Reviews in Pharmacy, 11 (5), 535-555. doi:10.31838/srp.2020.5.71 |
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